The Last Shadow Puppets perform tracks from their chart-topping album Everything You've Come to Expect. Bonnie Raitt returns to the show to run through some of the songs from her recently released twentieth album Dig in Deep, which features a healthy dose of the signature slide work from the woman Rolling Stone named one of the 100 greatest guitarists of all time. Malian kora player Ballake Sissoko and French cellist Vincent Segal have pulled two seemingly incompatible instruments together to great effect on their second album together. NAO makes her TV debut with her neo-soul, electro and R&B sound that has already seen her nominated for a MOBO award. Another act making their debut on the show are Dinosaur Jr. They earned themselves a reputation as one of the formative influences on US alt-rock in the 80s and early 90s. Completing the line-up is Zucchero, credited as the 'father of the Italian blues'.